| James Addison Baker | Kiev | Met with President Kravchuk. | December 18–19, 1991 |
| Warren Minor Christopher | Kiev | Met with President Kravchuk and senior Ukrainian officials. | October 24–26, 1993 |
| Warren Minor Christopher | Kiev | Accompanied President Clinton to a meeting with President Kravchuk. | January 12, 1994 |
| Warren Minor Christopher | Kiev | Accompanied President Clinton on state visit. | May 11–12, 1995 |
| Warren Minor Christopher | Kiev | Met with President Kuchma and Foreign Minister Udovenko. | March 18–19, 1996 |
| Madeleine Korbel Albright | Kiev | Met with President Kuchma and signed nuclear cooperation agreement. | March 6, 1998 |
| Madeleine Korbel Albright | Kiev | Met with President Kuchma and Foreign Minister Trasyuk. | April 14–15, 2000 |
| Colin Luther Powell | Kiev | Attended the inauguration of President Yushchenko. | January 22–23, 2005 |
| Condoleezza Rice | Kiev | Met with President Yushchenko and addressed students at Shevchenko
University. | December 6–7, 2005 |
| Condoleezza Rice | Kyiv | Joined President Bush. | March 31, 2008 |
| Hillary Rodham Clinton | Kyiv | Met with President Yanukovych and Foreign Minister Hryshchenko. Attended the second
meeting of the U.S.-Ukraine Strategic Partnership. | July 1–2, 2010 |
| John Forbes Kerry | Kyiv | Met with Acting President Oleksandr Turchynov, Prime Minister Arseniy Yatsenyuk,
and political and religious leaders. | March 4, 2014 |
| John Forbes Kerry | Kyiv | Met with President Petro Poroshenko and Prime Minister Arseniy Yatsenyuk. | February 5–6, 2015 |
| John Forbes Kerry | Kyiv | Met with President Petro Porochenko and Prime Minister Volodymyr
Groysman. | July 7, 2016 |
| Rex W. Tillerson | Kyiv | Met with President Petro Poroshenko. | July 9, 2017 |
| Michael R. Pompeo | Kyiv | Met with President Zelenskyy, Foreign Minister Prystaiko, and Defense Minister
Zahorodnyuk. | January 30, 2020 |
| Antony Blinken | Kyiv | Met with President Zelenskyy and Foreign Minister Kuleba. | May 5–6, 2021 |
| Antony Blinken | Kyiv | Met with President Volodymyr Zelenskyy and Foreign Minister Dmytro
Kuleba. | January 18–20, 2022 |
| Antony Blinken | Kiev | Visited with Secretary of Defense Lloyd J. Austin III and met with President
Volodymyr Zelenskyy, Foreign Minister Dmytro Kuleba, Defense Minister Oleksiy Reznikov,
and other senior officials. | April 24–25, 2022 |
| Antony Blinken | Kiev | Met with President Volodymyr Zelenskyy and Foreign Minister Dmytro
Kuleba. | September 8–9, 2022 |
| Antony Blinken | Kyiv | Met with President Volodymyr Zelenskyy, Prime Minister Denys Shmyhal, and Foreign
Minister Dmytro Kuleba. | September 6, 2023 |
