S - Principals and Chiefs Alphabetical
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Principal Officers and Chiefs of Mission, by Name: S
NOTE TO READERS
Updates to the Principal Officers and Chiefs of Mission database are currently suspended. For information about the Department’s current and recent leadership, we recommend visiting the Department of State homepage’s Biographies of Senior Officials and List of U.S. Ambassadors.
Notice posted on January 12, 2024.
Last
updated March 14, 2024.
Note: Career Foreign Service appointees are asterisked.
- *Leonard John Saccio (1911–)
- Ambassador Extraordinary and Plenipotentiary, Colombia (1970–1973)
- Leo R. Sack (1889–1956)
- Envoy Extraordinary and Minister Plenipotentiary, Costa Rica (1933–1937)
- Frederic Mosley Sackett (1868–1941)
- Ambassador Extraordinary and Plenipotentiary, Germany (1930–1933)
- Nathan Alexander Sales (1974–)
- Director of the Bureau of Counterterrorism (2017)
- Nicolas M. Salgo (1914–2005)
- Ambassador Extraordinary and Plenipotentiary, Hungary (1983–1986)
- Ambassador Extraordinary and Plenipotentiary, Sweden (Nomination of June 16, 1992, not acted upon by the Senate.)
- *Charles B. Salmon Jr. (1938–)
- Chargé d’Affaires, Laos (1992)
- Ambassador Extraordinary and Plenipotentiary, Laos (1992–1993)
- *Joseph A. Saloom III (1948–)
- Ambassador Extraordinary and Plenipotentiary, Guinea (1993–1996)
- *Bryant J. Salter (1950–)
- Chargé d’Affaires ad interim, Antigua and Barbuda (1994)
- Chargé d’Affaires ad interim, Saint Kitts and Nevis (1994)
- Charles Eckridge Saltzman (1903–1994)
- Assistant Secretary of State for Occupied Areas (1947–1949)
- Under Secretary of State for Management (1954)
- Herbert Salzman (1916–1990)
- Representative of the U.S.A. to the Organization for Economic Cooperation and Development (Paris) (1977–1981)
- *Dorothy Myers Sampas (1933–)
- Ambassador Extraordinary and Plenipotentiary, Mauritania (1994–1997)
- Archibald Johnson Sampson (1839–1921)
- Envoy Extraordinary and Minister Plenipotentiary, Ecuador (1897–1905)
- Michael Anthony Samuels (1939–)
- Ambassador Extraordinary and Plenipotentiary, Sierra Leone (1974–1977)
- Nathaniel Samuels (1908–1999)
- Deputy Under Secretary of State for Economic Affairs (1969–1972)
- Phillip Victor Sanchez (1929–)
- Ambassador Extraordinary and Plenipotentiary, Honduras (1973–1976)
- Ambassador Extraordinary and Plenipotentiary, Colombia (1976–1977)
- David B. Sandalow (1957–)
- Assistant Secretary of State for Oceans and International Environmental and Scientific Affairs (1999–2001)
- *Robin Renee Sanders (1954–)
- Ambassador Extraordinary and Plenipotentiary, Congo (Brazzaville) (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (2007–2010)
- *Janet Ann Sanderson (1955–)
- Ambassador Extraordinary and Plenipotentiary, Algeria (2000–2003)
- Ambassador Extraordinary and Plenipotentiary, Haiti (2006–2008)
- Carla H. Sands (?–)
- Ambassador Extraordinary and Plenipotentiary, Denmark (2017)
- William Franklin Sands (1874–1946)
- Envoy Extraordinary and Minister Plenipotentiary, Guatemala (1909–1910)
- Henry Shelton Sanford (1823–1891)
- Minister Resident, Belgium (1861–1869)
- Envoy Extraordinary and Minister Plenipotentiary, Belgium (Nomination of December 17, 1866, rejected by the Senate.)
- Envoy Extraordinary and Minister Plenipotentiary, Belgium (Nomination of March 8, 1867, rejected by the Senate.)
- Minister Resident, Belgium (Not commissioned; nomination not confirmed by the Senate.)
- Minister Resident, Spain (Not commissioned; nomination not confirmed by the Senate.)
- David Nathan Saperstein (1947–)
- Ambassador at Large (2015–2017)
- Howland Hill Sargeant (1911–1984)
- Assistant Secretary of State for Public Affairs (1952–1953)
- Aaron Augustus Sargent (1827–1887)
- Envoy Extraordinary and Minister Plenipotentiary, Germany (1882–1884)
- Envoy Extraordinary and Minister Plenipotentiary, Russia (Not commissioned although nomination was confirmed by the Senate.)
- *Karen H. Sasahara (?–)
- Chargé d’Affaires ad interim, Jordan (2019–2020)
- James R. Sasser (1936–)
- Ambassador Extraordinary and Plenipotentiary, China (1995–1999)
- *David Michael Satterfield (1954–)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Jordan (2004)
- Ambassador Extraordinary and Plenipotentiary, Turkey (2019)
- *Joseph Charles Satterthwaite (1900–1990)
- Ambassador Extraordinary and Plenipotentiary, Sri Lanka (1949–1953)
- Diplomatic Agent/Consul General, Morocco (1953–1955)
- Ambassador Extraordinary and Plenipotentiary, Burma (1955–1957)
- Director General of the Foreign Service (1957–1958)
- Assistant Secretary of State for African Affairs (1958–1961)
- Ambassador Extraordinary and Plenipotentiary, South Africa (1961–1965)
- Ellen Richmond Sauerbrey (1937–)
- Assistant Secretary of State for Population, Refugees, and Migration Affairs (2006–2007)
- *Harold Henry Saunders (1930–2016)
- Assistant Secretary of State for Intelligence and Research (1975–1978)
- Assistant Secretary of State for Near Eastern Affairs (1978–1981)
- Romulus Mitchell Saunders (1791–1867)
- Envoy Extraordinary and Minister Plenipotentiary, Spain (1846–1849)
- Charles Sawyer (1887–1979)
- Ambassador Extraordinary and Plenipotentiary, Belgium (1944–1945)
- Envoy Extraordinary and Minister Plenipotentiary, Luxembourg (1944–1945)
- William Bart Saxbe (1916–2010)
- Ambassador Extraordinary and Plenipotentiary, India (1975–1976)
- Francis Bowes Sayre (1885–1972)
- Assistant Secretary of State (1933–1939)
- *Robert Marion Sayre (1924–2016)
- Ambassador Extraordinary and Plenipotentiary, Uruguay (1968–1969)
- Ambassador Extraordinary and Plenipotentiary, Panama (1969–1974)
- Inspector General of the Department of State and the Foreign Service (1975–1978)
- Ambassador Extraordinary and Plenipotentiary, Brazil (1978–1981)
- Director of the Bureau of Counterterrorism (1982–1984)
- John Alfred Scali (1918–1995)
- Representative of the U.S.A. to the United Nations (1973–1975)
- *John Douglas Scanlan (1927–2007)
- Ambassador Extraordinary and Plenipotentiary, Socialist Federal Republic of Yugoslavia (1985–1989)
- *Michael D. Scanlan (1961–)
- Chargé d’Affaires, Belarus (2013)
- *Eugene L. Scassa (1939–2012)
- Ambassador Extraordinary and Plenipotentiary, Belize (1990–1994)
- John Robert Schaetzel (1917–2003)
- Representative of the U.S.A. to the European Union, with the rank and status of Ambassador Extraordinary and Plenipotentiary (1966–1972)
- *M. Virginia Schafer (1931–)
- Ambassador Extraordinary and Plenipotentiary, Solomon Islands (1981–1984)
- Ambassador Extraordinary and Plenipotentiary, Papua New Guinea (1981–1984)
- *Howard Bruner Schaffer (1929–2017)
- Ambassador Extraordinary and Plenipotentiary, Bangladesh (1984–1987)
- *Teresita Currie Schaffer (1945–)
- Ambassador Extraordinary and Plenipotentiary, Maldives (1992–1995)
- Ambassador Extraordinary and Plenipotentiary, Sri Lanka (1992–1995)
- Director of the Foreign Service Institute (1995–1997)
- Andrew H. Schapiro (1963–)
- Ambassador Extraordinary and Plenipotentiary, Czech Republic (2014–2017)
- *Mark A. Schapiro (?–)
- Chargé d’Affaires ad interim, Malta (2018–2020)
- *William Everett Schaufele Jr. (1923–2008)
- Ambassador Extraordinary and Plenipotentiary, Burkina Faso (1969–1971)
- Inspector General of the Department of State and the Foreign Service (1975)
- Assistant Secretary of State for African Affairs (1975–1977)
- Ambassador Extraordinary and Plenipotentiary, Greece (1977)
- Ambassador Extraordinary and Plenipotentiary, Poland (1978–1980)
- Arthur Louis Schechter (1939–)
- Ambassador Extraordinary and Plenipotentiary, The Bahamas (1998–2001)
- David J. Scheffer (1953–)
- Ambassador at Large (1997–2001)
- Robert Cumming Schenck (1809–1890)
- Envoy Extraordinary and Minister Plenipotentiary, Brazil (1851–1853)
- Envoy Extraordinary and Minister Plenipotentiary, United Kingdom (1870–1876)
- David Schenker (?–)
- Assistant Secretary of State for Near Eastern Affairs (2019)
- *Lange Schermerhorn (1939–)
- Ambassador Extraordinary and Plenipotentiary, Djibouti (1997–2000)
- John Thomas Schieffer (1947–)
- Ambassador Extraordinary and Plenipotentiary, Australia (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Japan (2005–2009)
- Richard Schifter (1923–)
- Assistant Secretary of State for Democracy, Human Rights, and Labor (1985–1992)
- *Ronald Lewis Schlicher (1958–)
- Chargé d’Affaires ad interim, Lebanon (1996)
- Ambassador Extraordinary and Plenipotentiary, Cyprus (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Tunisia (Nomination not acted upon by the Senate.)
- Albert George Schmedemann (1864–1946)
- Envoy Extraordinary and Minister Plenipotentiary, Norway (1913–1921)
- Adolph William Schmidt (1904–2000)
- Ambassador Extraordinary and Plenipotentiary, Canada (1969–1974)
- *Richard J. Schmierer (1950–)
- Ambassador Extraordinary and Plenipotentiary, Oman (2009–2012)
- Rockwell Anthony Schnabel (1936–)
- Ambassador Extraordinary and Plenipotentiary, Finland (1985–1989)
- Representative of the U.S.A. to the European Union, with the rank and status of Ambassador Extraordinary and Plenipotentiary (2001–2005)
- Cynthia Perrin Schneider (1953–)
- Ambassador Extraordinary and Plenipotentiary, Netherlands (1998–2001)
- *David Taylor Schneider (1922–2014)
- Ambassador Extraordinary and Plenipotentiary, Bangladesh (1978–1981)
- George Schneider (1823–1905)
- Chargé d’Affaires, Switzerland (1877)
- William Schneider Jr. (1941–)
- Under Secretary of State for Arms Control and International Security Affairs (1982–1986)
- *Hans Frederick Arthur Schoenfeld (1889–1952)
- Envoy Extraordinary and Minister Plenipotentiary, Bulgaria (1928)
- Envoy Extraordinary and Minister Plenipotentiary, Costa Rica (1929)
- Envoy Extraordinary and Minister Plenipotentiary, Dominican Republic (1931–1937)
- Envoy Extraordinary and Minister Plenipotentiary, Finland (1937–1942)
- Envoy Extraordinary and Minister Plenipotentiary, Hungary (1945–1947)
- *Rudolf Emil Schoenfeld (1895–1981)
- Chargé d’Affaires ad interim, Belgium (1944)
- Chargé d’Affaires, Luxembourg (1944)
- Chargé d’Affaires ad interim, Poland (1945)
- Envoy Extraordinary and Minister Plenipotentiary, Romania (1947–1950)
- Ambassador Extraordinary and Plenipotentiary, Guatemala (1951–1953)
- Ambassador Extraordinary and Plenipotentiary, Colombia (1953–1955)
- Chargé d’Affaires ad interim, Belgium (Served as Chargé d’Affaires ad interim near the Government of Belgium established in England.)
- Chargé d’Affaires ad interim, Norway ()
- Chargé d’Affaires ad interim, Belgium (Schoenfeld established the Legation near the Government of the Netherlands in the United Kingdom.)
- *Brenda Schoonover (1939–)
- Ambassador Extraordinary and Plenipotentiary, Togo (1997–2000)
- *Stanley N. Schrager (1941–)
- Chargé d’Affaires ad interim, Mauritania (1982)
- Ambassador Extraordinary and Plenipotentiary, Djibouti (Nomination of May 6, 1996, was withdrawn.)
- Francis Schroeder (1814–1886)
- Chargé d’Affaires, Sweden (1849–1854)
- Minister Resident, Sweden (1854–1857)
- Gregory L. Schulte (1958–)
- Representative of the U.S.A. to the Vienna Office of the United Nations (Vienna) (2005–2009)
- Representative of the U.S.A. to the International Atomic Energy Agency (Vienna) (2005–2009)
- *Eric T. Schultz (1959–)
- Ambassador Extraordinary and Plenipotentiary, Zambia (2014–2017)
- Jacob Gould Schurman (1854–1942)
- Envoy Extraordinary and Minister Plenipotentiary, Greece (1912–1913)
- Envoy Extraordinary and Minister Plenipotentiary, Montenegro (1912–1913)
- Envoy Extraordinary and Minister Plenipotentiary, China (1921–1925)
- Ambassador Extraordinary and Plenipotentiary, Germany (1925–1930)
- Carl Schurz (1829–1906)
- Envoy Extraordinary and Minister Plenipotentiary, Spain (1861)
- Eugene Schuyler (1840–1890)
- Diplomatic Agent/Consul General, Romania (1880–1881)
- Chargé d’Affaires and Consul General, Romania (1880–1882)
- Minister Resident/Consul General, Greece (1882–1884)
- Minister Resident/Consul General, Serbia (1882–1884)
- Minister Resident/Consul General, Romania (1882–1884)
- Agent/Consul General, Egypt (1889–1890)
- Assistant Secretary of State (Not commissioned; nomination withdrawn before the Senate acted upon it.)
- Montgomery Schuyler Jr. (1877–1955)
- Envoy Extraordinary and Minister Plenipotentiary, Ecuador (1913)
- Envoy Extraordinary and Minister Plenipotentiary, El Salvador (1921–1925)
- Abba Philip Schwartz (1916–1989)
- Assistant Secretary of State for Consular Affairs (1962–1966)
- Eric P. Schwartz (1957–)
- Assistant Secretary of State for Population, Refugees, and Migration Affairs (2009–2011)
- *Stephen Michael Schwartz (1958–)
- Chargé d’Affaires ad interim, Comoros (2006)
- Chargé d’Affaires ad interim, Seychelles (2006)
- Chargé d’Affaires ad interim, Mauritius (2006)
- Ambassador Extraordinary and Plenipotentiary, Somalia (2016–2017)
- William B. Schwartz Jr. (1921–2010)
- Ambassador Extraordinary and Plenipotentiary, The Bahamas (1977–1981)
- *Margaret Scobey (1949–)
- Ambassador Extraordinary and Plenipotentiary, Syria (2003–2005)
- Ambassador Extraordinary and Plenipotentiary, Egypt (2008–2011)
- *Thomas James Scotes (1932–)
- Chargé d’Affaires ad interim, Syria (1974)
- Ambassador Extraordinary and Plenipotentiary, Yemen (1974–1978)
- Charles Lewis Scott (1827–1899)
- Minister Resident/Consul General, Venezuela (1885–1888)
- Envoy Extraordinary and Minister Plenipotentiary, Venezuela (1888–1889)
- *Gerald Wesley Scott (1940–)
- Ambassador Extraordinary and Plenipotentiary, The Gambia (1995–1998)
- *Kyle R. Scott (1957–)
- Ambassador Extraordinary and Plenipotentiary, Serbia (2015–2019)
- *Robert K. Scott (?–)
- Ambassador Extraordinary and Plenipotentiary, Malawi (2019)
- Stuart Nash Scott (1906–1991)
- Ambassador Extraordinary and Plenipotentiary, Portugal (1973–1975)
- *Walter Kenneth Scott (1915–1977)
- Assistant Secretary of State for Administration (1958–1959)
- *Robert McGregor Scotten (1891–1968)
- Envoy Extraordinary and Minister Plenipotentiary, Dominican Republic (1940–1942)
- Envoy Extraordinary and Minister Plenipotentiary, Costa Rica (1942–1943)
- Ambassador Extraordinary and Plenipotentiary, Ecuador (1943–1947)
- Envoy Extraordinary and Minister Plenipotentiary, New Zealand (1947–1948)
- Ambassador Extraordinary and Plenipotentiary, New Zealand (1948–1955)
- William Warren Scranton (1917–2013)
- Representative of the U.S.A. to the United Nations (1976–1977)
- William Lindsay Scruggs (1836–1912)
- Minister Resident, Colombia (1873–1876)
- Minister Resident, Colombia (1882–1884)
- Envoy Extraordinary and Minister Plenipotentiary, Colombia (1884–1885)
- Envoy Extraordinary and Minister Plenipotentiary, Venezuela (1889–1892)
- William A. Seay (1831–1888)
- Minister Resident/Consul General, Bolivia (1885–1887)
- *William Joseph Sebald (1901–1980)
- Ambassador Extraordinary and Plenipotentiary, Burma (1952–1954)
- Ambassador Extraordinary and Plenipotentiary, Australia (1957–1961)
- *Peter Sebastian (1926–2011)
- Ambassador Extraordinary and Plenipotentiary, Tunisia (1984–1987)
- Peter F. Secchia (1937–)
- Ambassador Extraordinary and Plenipotentiary, Italy (1989–1993)
- *Stephen A. Seche (1948–)
- Chargé d’Affaires ad interim, Syria (2006)
- Ambassador Extraordinary and Plenipotentiary, Yemen (2007–2010)
- Theodore Sedgwick (1948–)
- Ambassador Extraordinary and Plenipotentiary, Slovakia (2010–2015)
- *Talcott Williams Seelye (1922–2006)
- Ambassador Extraordinary and Plenipotentiary, Tunisia (1972–1976)
- Ambassador Extraordinary and Plenipotentiary, Syria (1978–1981)
- *Joseph Monroe Segars (1938–)
- Ambassador Extraordinary and Plenipotentiary, Cape Verde (1992–1996)
- John Jacob Seibels (1816–1865)
- Chargé d’Affaires, Belgium (1853–1854)
- Minister Resident, Belgium (1854–1856)
- Envoy Extraordinary and Minister Plenipotentiary, Belgium (Nomination of February 25, 1856, withdrawn before the Senate acted upon it.)
- George Marion Seignious II (1921–2005)
- Director of the U.S. Arms Control and Disarmament Agency (1978–1980)
- Robert A. Seiple (1942–)
- Ambassador at Large (1999–2000)
- *Raymond George Hardenbergh Seitz (1940–)
- Assistant Secretary of State for European and Eurasian Affairs (1989–1991)
- Ambassador Extraordinary and Plenipotentiary, United Kingdom (1991–1994)
- Armistead Inge Selden Jr. (1921–1985)
- Ambassador Extraordinary and Plenipotentiary, Fiji (1974–1978)
- Ambassador Extraordinary and Plenipotentiary, Tonga (1974–1979)
- Ambassador Extraordinary and Plenipotentiary, Samoa (1974–1979)
- Ambassador Extraordinary and Plenipotentiary, New Zealand (1974–1979)
- Peter A. Selfridge (1971–)
- Chief of Protocol (2014–2016)
- Ivan Selin (1937–)
- Under Secretary of State for Management (1989–1991)
- Melvin Floyd Sembler (1930–)
- Ambassador Extraordinary and Plenipotentiary, Australia (1989–1993)
- Ambassador Extraordinary and Plenipotentiary, Nauru (1989–1993)
- Ambassador Extraordinary and Plenipotentiary, Italy (2001–2005)
- James Semple (1798–1866)
- Chargé d’Affaires, Colombia (1837–1842)
- *Michael James Senko (1950–)
- Ambassador Extraordinary and Plenipotentiary, Kiribati (2000–2003)
- Ambassador Extraordinary and Plenipotentiary, Marshall Islands (2000–2003)
- *Robert Edward Service (1937–)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (1994–1997)
- Edson Oliver Sessions (1902–1987)
- Ambassador Extraordinary and Plenipotentiary, Finland (1959–1960)
- Ambassador Extraordinary and Plenipotentiary, Ecuador (1968–1970)
- Stephen R. Sestanovich (1950–)
- Ambassador at Large (1997–2001)
- Thomas Settle (1831–1888)
- Envoy Extraordinary and Minister Plenipotentiary, Peru (1871)
- Henry Hulme Sevier (1878–1940)
- Ambassador Extraordinary and Plenipotentiary, Chile (1933–1935)
- Harold Marsh Sewall (1860–1924)
- Envoy Extraordinary and Minister Plenipotentiary, Hawaii (1897–1898)
- Sarah Sewall (1961–)
- Under Secretary of State for Civilian Security, Democracy, and Human Rights (2014–2017)
- Frederick William Seward (1830–1915)
- Assistant Secretary of State (1861–1869)
- Assistant Secretary of State (1877–1879)
- George Frederick Seward (1840–1910)
- Envoy Extraordinary and Minister Plenipotentiary, China (1876–1880)
- William Henry Seward (1801–1872)
- Secretary of State (1861–1869)
- Thomas Hart Seymour (1807–1868)
- Envoy Extraordinary and Minister Plenipotentiary, Russia (1853–1858)
- John Seys (1799–1872)
- Minister Resident/Consul General, Liberia (1866–1870)
- John Shad (1923–1994)
- Ambassador Extraordinary and Plenipotentiary, Netherlands (1987–1989)
- Frank J. Shakespeare Jr. (1925–)
- Director of the U.S. Information Agency (1969–1973)
- Ambassador Extraordinary and Plenipotentiary, Portugal (1985–1986)
- Ambassador Extraordinary and Plenipotentiary, Holy See (1986–1989)
- *Nicole D. Shampaine (?–)
- Chargé d’Affaires ad interim (2017–2018)
- Chargé d’Affaires ad interim (2017–2018)
- James Shannon (1791–1832)
- Chargé d’Affaires, Guatemala (1832)
- Richard Cutts Shannon (1839–1920)
- Envoy Extraordinary and Minister Plenipotentiary, El Salvador (1891–1893)
- Envoy Extraordinary and Minister Plenipotentiary, Costa Rica (1891–1893)
- Envoy Extraordinary and Minister Plenipotentiary, Nicaragua (1891–1893)
- *Thomas Alfred Shannon Jr. (1958–)
- Assistant Secretary of State for Western Hemisphere Affairs (2005–2009)
- Ambassador Extraordinary and Plenipotentiary, Brazil (2009–2013)
- Career Ambassador (2012)
- Counselor (2013–2016)
- Under Secretary of State for Political Affairs (2016–2018)
- Secretary of State ad interim (2017)
- William Vincent Shannon (1927–1988)
- Ambassador Extraordinary and Plenipotentiary, Ireland (1977–1981)
- Wilson Shannon (1802–1877)
- Envoy Extraordinary and Minister Plenipotentiary, Mexico (1844–1845)
- *Harold Shantz (1894–1967)
- Envoy Extraordinary and Minister Plenipotentiary, Romania (1952–1955)
- Andrew J. Shapiro (1967–)
- Assistant Secretary of State for Politico-Military Affairs (2009–2013)
- *Charles S. Shapiro (1949–)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (2002–2004)
- Daniel B. Shapiro (1969–)
- Ambassador Extraordinary and Plenipotentiary, Israel (2011–2017)
- William Graves Sharp (1859–1922)
- Ambassador Extraordinary and Plenipotentiary, France (1914–1919)
- *Mattie R. Sharpless (1943–)
- Ambassador Extraordinary and Plenipotentiary, Central African Republic (2001–2002)
- John Howard Francis Shattuck (1943–)
- Assistant Secretary of State for Democracy, Human Rights, and Labor (1993–1998)
- Ambassador Extraordinary and Plenipotentiary, Czech Republic (1998–2000)
- *Gardiner Howland Shaw (1893–1965)
- Assistant Secretary of State (1941–1944)
- *George Price Shaw (1892–1966)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (1948–1949)
- Ambassador Extraordinary and Plenipotentiary, El Salvador (1949–1952)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (1952–1953)
- John Arthur Shaw (1939–)
- Inspector General of Foreign Assistance (1976–1977)
- *Dorothy Shea (?–)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (2020)
- Joseph Hooker Shea (1863–1928)
- Ambassador Extraordinary and Plenipotentiary, Chile (1916–1921)
- Owen James Sheaks (1943–)
- Assistant Secretary of State for Arms Control, Verification, and Compliance (2000–2002)
- *David Bruce Shear (1954–)
- Ambassador Extraordinary and Plenipotentiary, Vietnam (2011–2014)
- Derek Shearer (1946–)
- Ambassador Extraordinary and Plenipotentiary, Finland (1994–1997)
- Michael E. Sheehan (1955–)
- Director of the Bureau of Counterterrorism (1999–2000)
- Ambassador at Large (1999–2000)
- James Rockwell Sheffield (1864–1938)
- Ambassador Extraordinary and Plenipotentiary, Mexico (1924–1927)
- *Gilbert H. Sheinbaum (1929–)
- Chargé d’Affaires ad interim, Madagascar (1977)
- Samuel Shellabarger (1817–1896)
- Minister Resident, Portugal (1869–1870)
- Sally Angela Shelton (1944–)
- Ambassador Extraordinary and Plenipotentiary, Dominica (1979–1981)
- Ambassador Extraordinary and Plenipotentiary, Barbados (1979–1981)
- Ambassador Extraordinary and Plenipotentiary, Grenada (1979–1981)
- Envoy Extraordinary and Minister Plenipotentiary, Saint Lucia (1979–1981)
- *Turner Blair Shelton (1915–1982)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (1970–1975)
- *Albert William Sherer Jr. (1916–1986)
- Ambassador Extraordinary and Plenipotentiary, Togo (1967–1970)
- Ambassador Extraordinary and Plenipotentiary, Equatorial Guinea (1968–1969)
- Ambassador Extraordinary and Plenipotentiary, Guinea (1970–1971)
- Ambassador Extraordinary and Plenipotentiary, Czechoslovakia (1972–1975)
- Leo John Sheridan (1897–1975)
- Ambassador Extraordinary and Plenipotentiary, Ireland (1968–1969)
- John Sherman (1823–1900)
- Secretary of State (1897–1898)
- Robert A. Sherman (1953–)
- Ambassador Extraordinary and Plenipotentiary, Portugal (2014–2017)
- Wendy R. Sherman (1949–)
- Assistant Secretary of State for Legislative Affairs (1993–1996)
- Counselor (1997–2001)
- Under Secretary of State for Political Affairs (2011–2015)
- Charles Hitchcock Sherrill (1867–1936)
- Envoy Extraordinary and Minister Plenipotentiary, Argentina (1909–1910)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1932–1933)
- Benjamin Glover Shields (1808–1850)
- Chargé d’Affaires, Venezuela (1845–1850)
- *Daniel L. Shields 3rd (1963–)
- Ambassador Extraordinary and Plenipotentiary, Brunei (2011–2014)
- Josette Sheeran Shiner (1954–)
- Under Secretary for Economic Growth, Energy, and the Environment (2005–2007)
- *David H. Shinn (1940–)
- Ambassador Extraordinary and Plenipotentiary, Burkina Faso (1987–1990)
- Ambassador Extraordinary and Plenipotentiary, Ethiopia (1996–1999)
- *Amelia Ellen Shippy (1944–)
- Ambassador Extraordinary and Plenipotentiary, Malawi (1997–2000)
- *John William Shirley (1931–)
- Ambassador Extraordinary and Plenipotentiary, Tanzania (1984–1986)
- *Katherine Shirley (1942–)
- Ambassador Extraordinary and Plenipotentiary, Senegal (1991–1992)
- *Harry Walter Shlaudeman (1926–)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (1975–1976)
- Assistant Secretary of State for Western Hemisphere Affairs (1976–1977)
- Ambassador Extraordinary and Plenipotentiary, Peru (1977–1980)
- Ambassador Extraordinary and Plenipotentiary, Argentina (1980–1983)
- Ambassador at Large (1984–1986)
- Ambassador Extraordinary and Plenipotentiary, Brazil (1986–1989)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (1990–1992)
- Henry Wharton Shoemaker (1882–1958)
- Envoy Extraordinary and Minister Plenipotentiary, Bulgaria (1930–1933)
- *Thomas P. Shoesmith (1922–)
- Ambassador Extraordinary and Plenipotentiary, Malaysia (1983–1987)
- William Short (1759–1849)
- Minister Plenipotentiary, France (1790–1792)
- Minister Resident, Netherlands (1792)
- Minister Resident, Spain (1794–1795)
- Minister Plenipotentiary, Russia (1808)
- Robert Sargent Shriver Jr. (1915–2011)
- Ambassador Extraordinary and Plenipotentiary, France (1968–1970)
- *Adam M. Shub (?–)
- Chargé d’Affaires ad interim (2017–2018)
- *Brian Shukan (?–)
- Chargé d’Affaires, Sudan (2019)
- George Pratt Shultz (1920–2021)
- Secretary of State (1982–1989)
- Edward E. Shumaker III (1948–)
- Ambassador Extraordinary and Plenipotentiary, Trinidad and Tobago (1997–2001)
- *Leonard Grant Shurtleff (1940–2015)
- Ambassador Extraordinary and Plenipotentiary, Congo (Brazzaville) (1987–1990)
- *Justin H. Siberell (1966–)
- Ambassador Extraordinary and Plenipotentiary, Bahrain (2017–2020)
- Director of the Bureau of Counterterrorism (Nomination of September 19, 2016, not acted upon by the Senate.)
- Daniel Edgar Sickles (1825–1914)
- Minister Resident, Netherlands (1866)
- Envoy Extraordinary and Minister Plenipotentiary, Spain (1869–1874)
- M. Osman Siddique (1950–)
- Ambassador Extraordinary and Plenipotentiary, Fiji (1999–2001)
- Ambassador Extraordinary and Plenipotentiary, Tonga (1999–2001)
- Ambassador Extraordinary and Plenipotentiary, Nauru (1999–2001)
- Ambassador Extraordinary and Plenipotentiary, Tuvalu (1999–2001)
- Thomas L. Siebert (1946–)
- Ambassador Extraordinary and Plenipotentiary, Sweden (1994–1997)
- Ned L. Siegel (1951–)
- Ambassador Extraordinary and Plenipotentiary, The Bahamas (2007–2009)
- Nelson F. Sievering Jr. (1924–1997)
- Representative of the U.S.A. to the International Atomic Energy Agency (Vienna) (1993–1997)
- *Marc Jonathan Sievers (1955–)
- Ambassador Extraordinary and Plenipotentiary, Oman (2015–2019)
- *Anne Marie Sigmund (1946–)
- Ambassador Extraordinary and Plenipotentiary, Kyrgyzstan (1997–2000)
- Gaston Joseph Sigur Jr. (1924–1995)
- Assistant Secretary of State for East Asian and Pacific Affairs (1986–1989)
- Laurence Hirsch Silberman (1935–)
- Ambassador Extraordinary and Plenipotentiary, Socialist Federal Republic of Yugoslavia (1975–1976)
- *Ints M. Silins (1942–)
- Ambassador Extraordinary and Plenipotentiary, Latvia (1992–1995)
- Chargé d’Affaires ad interim, Latvia ()
- John Mahelm Berry Sill (1831–1901)
- Minister Resident/Consul General, Korea (1894–1897)
- *Douglas Alan Silliman (1960–)
- Ambassador Extraordinary and Plenipotentiary, Kuwait (2014–2016)
- Ambassador Extraordinary and Plenipotentiary, Iraq (2016–2019)
- Kristen Silverberg (1970–)
- Assistant Secretary of State for International Organization Affairs (2005–2008)
- Representative of the U.S.A. to the European Union, with the rank and status of Ambassador Extraordinary and Plenipotentiary (2008–2009)
- Joy A. Silverman (1947–)
- Ambassador Extraordinary and Plenipotentiary, Dominica (Nomination of July 11, 1989, not acted upon by the Senate.)
- Ambassador Extraordinary and Plenipotentiary, Barbados (Nomination of July 11, 1989, not acted upon by the Senate.)
- Ambassador Extraordinary and Plenipotentiary, Saint Vincent and the Grenadines (Nomination of July 11, 1989, not acted upon by the Senate.)
- Ambassador Extraordinary and Plenipotentiary, Saint Lucia (Nomination of July 11, 1989, not acted upon by the Senate.)
- *Lawrence R. Silverman (?–)
- Ambassador Extraordinary and Plenipotentiary, Kuwait (2016–2019)
- Martin J. Silverstein (1954–)
- Ambassador Extraordinary and Plenipotentiary, Uruguay (2001–2005)
- *David E. Simcox (1932–)
- Ambassador Extraordinary and Plenipotentiary, Mozambique (Not commissioned; nomination not acted upon by the Senate.)
- *John Farr Simmons (1892–1968)
- Ambassador Extraordinary and Plenipotentiary, El Salvador (1944–1947)
- Ambassador Extraordinary and Plenipotentiary, Ecuador (1947–1950)
- Chief of Protocol (1950–1957)
- *Hugh V. Simon Jr. (1944–)
- Chargé d’Affaires ad interim, Guyana (1997)
- John A. Simon (1968–)
- Representative of the U.S.A. to the African Union (2008–2009)
- *Paul E. Simons (1955–)
- Ambassador Extraordinary and Plenipotentiary, Chile (2007–2010)
- *Thomas W. Simons Jr. (1938–)
- Ambassador Extraordinary and Plenipotentiary, Poland (1990–1993)
- Ambassador Extraordinary and Plenipotentiary, Pakistan (1995–1998)
- Joseph Simonson (1904–1985)
- Ambassador Extraordinary and Plenipotentiary, Ethiopia (1953–1957)
- *Daniel Howard Simpson (1939–)
- Ambassador Extraordinary and Plenipotentiary, Central African Republic (1989–1992)
- Ambassador Extraordinary and Plenipotentiary, Congo (Kinshasa) (1995–1998)
- Manisha Singh (1971–)
- Assistant Secretary of State for Economic, Energy, and Business Affairs (2017)
- *Melvin E. Sinn (1924–2006)
- Chargé d’Affaires ad interim, Guatemala (1981)
- *Ernest Victor Siracusa (1918–2000)
- Ambassador Extraordinary and Plenipotentiary, Bolivia (1969–1973)
- Ambassador Extraordinary and Plenipotentiary, Uruguay (1973–1977)
- *Joseph John Sisco (1919–2004)
- Assistant Secretary of State for International Organization Affairs (1965–1969)
- Assistant Secretary of State for Near Eastern Affairs (1969–1974)
- Under Secretary of State for Political Affairs (1974–1976)
- *Michele Jeanne Sison (1959–)
- Ambassador Extraordinary and Plenipotentiary, United Arab Emirates (2004–2008)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (2008–2010)
- Ambassador Extraordinary and Plenipotentiary, Maldives (2012–2014)
- Ambassador Extraordinary and Plenipotentiary, Sri Lanka (2012–2014)
- Ambassador Extraordinary and Plenipotentiary, Haiti (2018)
- Career Ambassador (2018)
- *Robert Woltz Skiff (1923–1999)
- Chargé d’Affaires ad interim, Fiji ()
- Elliott Percival Skinner (1924–2007)
- Ambassador Extraordinary and Plenipotentiary, Burkina Faso (1966–1969)
- Kiron Skinner (?–)
- Director of Policy Planning (2018–2019)
- *Robert Peet Skinner (1866–1960)
- Envoy Extraordinary and Minister Plenipotentiary, Greece (1926–1932)
- Envoy Extraordinary and Minister Plenipotentiary, Estonia (1931–1933)
- Envoy Extraordinary and Minister Plenipotentiary, Latvia (1931–1933)
- Envoy Extraordinary and Minister Plenipotentiary, Lithuania (1931–1933)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1933–1936)
- *Emil M. Skodon (1953–)
- Ambassador Extraordinary and Plenipotentiary, Brunei (2005–2008)
- *Michael Martin Skol (1942–)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (1990–1993)
- *Kenneth N. Skoug Jr. (1931–)
- Chargé d’Affaires ad interim, Venezuela (1990)
- Anne-Marie Slaughter (1958–)
- Director of Policy Planning (2009–2011)
- John Slidell (1793–1871)
- Envoy Extraordinary and Minister Plenipotentiary, Mexico (1845)
- Envoy Extraordinary and Minister Plenipotentiary, El Salvador (1853)
- Envoy Extraordinary and Minister Plenipotentiary, Costa Rica (1853)
- Envoy Extraordinary and Minister Plenipotentiary, Honduras (1853)
- Envoy Extraordinary and Minister Plenipotentiary, Guatemala (1853)
- Envoy Extraordinary and Minister Plenipotentiary, Nicaragua (1853)
- *Alexander Kilgore Sloan (1882–1944)
- Chargé d’Affaires, Iraq (1931–1932)
- *Pamela Jo Howell Slutz (1949–)
- Ambassador Extraordinary and Plenipotentiary, Mongolia (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Burundi (2009–2012)
- Robert M. Smalley (1925–2012)
- Ambassador Extraordinary and Plenipotentiary, Lesotho (1987–1989)
- Charles Emory Smith (1842–1908)
- Envoy Extraordinary and Minister Plenipotentiary, Russia (1890–1892)
- *Dana Shell Smith (1970–)
- Ambassador Extraordinary and Plenipotentiary, Qatar (2014–2017)
- *Dane Farnsworth Smith Jr. (1940–)
- Ambassador Extraordinary and Plenipotentiary, Guinea (1990–1993)
- Ambassador Extraordinary and Plenipotentiary, Senegal (1996–1999)
- *Daniel Bennett Smith (1956–)
- Executive Secretary (2007–2009)
- Ambassador Extraordinary and Plenipotentiary, Greece (2010–2013)
- Assistant Secretary of State for Intelligence and Research (2014–2018)
- Director of the Foreign Service Institute (2018)
- Career Ambassador (2018)
- Secretary of State ad interim (2021)
- David Shiverick Smith (1918–2012)
- Ambassador Extraordinary and Plenipotentiary, Sweden (1976–1977)
- Earl Edward Tailer Smith (1903–1991)
- Ambassador Extraordinary and Plenipotentiary, Cuba (1957–1959)
- Ezekiel Ezra Smith (1852–1933)
- Minister Resident/Consul General, Liberia (1888–1890)
- *Gentry O. Smith (1959–)
- Director of the Office of Foreign Missions (2015–2017)
- Gerard Coad Smith (1914–1994)
- Director of Policy Planning (1957–1961)
- Director of the U.S. Arms Control and Disarmament Agency (1969–1973)
- Representative of the U.S.A. to the International Atomic Energy Agency (Vienna) (1977–1980)
- Ambassador at Large (1977–1980)
- *Horace Harrison Smith (1905–1976)
- Ambassador Extraordinary and Plenipotentiary, Laos (1958–1960)
- James B. Smith (1952–)
- Ambassador Extraordinary and Plenipotentiary, Saudi Arabia (2009–2013)
- James Hopkins Smith Jr. (1909–1982)
- Director of the International Cooperation Administration (1957–1959)
- Jean Kennedy Smith (1928–)
- Ambassador Extraordinary and Plenipotentiary, Ireland (1993–1998)
- John Cotton Smith II (1810–1879)
- Minister Resident, Bolivia (1858–1861)
- *Keith C. Smith (1938–)
- Ambassador Extraordinary and Plenipotentiary, Lithuania (1997–2000)
- Madison Roswell Smith (1850–1919)
- Envoy Extraordinary and Minister Plenipotentiary, Haiti (1913–1914)
- Nicholas Smith (?–)
- Minister Resident, Greece (Not commissioned; nomination withdrawn before the Senate acted upon it.)
- *Norman Shaw Smith (1936–)
- Chargé d’Affaires ad interim, Uruguay (1981)
- Owen Lun West Smith (1851–1926)
- Minister Resident/Consul General, Liberia (1898–1902)
- *Pamela Hyde Smith (1945–)
- Ambassador Extraordinary and Plenipotentiary, Moldova (2001–2003)
- Paul Albert Smith (1901–1978)
- Representative of the U.S.A. on the Council of the International Civil Aviation Organization (Montreal) (1948–1953)
- *R. Grant Smith (1939–)
- Ambassador Extraordinary and Plenipotentiary, Tajikistan (1995–1998)
- Robert Smith (1757–1842)
- Secretary of State (1809–1811)
- *Robert Powell Smith (1929–2012)
- Ambassador Extraordinary and Plenipotentiary, Malta (1974–1976)
- Ambassador Extraordinary and Plenipotentiary, Ghana (1976–1979)
- Ambassador Extraordinary and Plenipotentiary, Liberia (1979–1981)
- Robert Solwin Smith (1924–2013)
- Ambassador Extraordinary and Plenipotentiary, Côte d’Ivoire (1974–1976)
- *Thomas William Macauley Smith (1930–1987)
- Ambassador Extraordinary and Plenipotentiary, Ghana (1979–1983)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (1984–1986)
- Walter Bedell Smith (1895–1961)
- Ambassador Extraordinary and Plenipotentiary, Russia (1946–1948)
- Under Secretary of State (1953–1954)
- *Wayne S. Smith (1932–)
- Principal Officer, Cuba (1982)
- William Loughton Smith (1758–1812)
- Minister Plenipotentiary, Portugal (1797–1801)
- Marion Hartzog Smoak (1916–)
- Chief of Protocol (1974)
- Henry DeWolf Smyth (1898–1986)
- Representative of the U.S.A. to the International Atomic Energy Agency (Vienna) (1961–1970)
- John Henry Smyth (1844–1908)
- Minister Resident/Consul General, Liberia (1878–1881)
- Minister Resident/Consul General, Liberia (1882–1885)
- *Reece Smyth (?–)
- Chargé d’Affaires ad interim, Ireland (2019)
- Henry A. Smythe (?–)
- Envoy Extraordinary and Minister Plenipotentiary, Austria (Not commissioned; nomination rejected by the Senate.)
- Envoy Extraordinary and Minister Plenipotentiary, Russia (Not commissioned; nomination tabled by the Senate.)
- Henry Maxwell Smythe (1844–1932)
- Chargé d’Affaires, Dominican Republic (1893–1897)
- Minister Resident/Consul General, Haiti (1893–1897)
- Hugh Heyne Smythe (1913–1977)
- Ambassador Extraordinary and Plenipotentiary, Syria (1965–1967)
- Ambassador Extraordinary and Plenipotentiary, Malta (1967–1969)
- Mabel Murphy Smythe (1918–2006)
- Ambassador Extraordinary and Plenipotentiary, Cameroon (1977–1980)
- Ambassador Extraordinary and Plenipotentiary, Equatorial Guinea (1979–1980)
- *Richard Lee Sneider (1922–1986)
- Ambassador Extraordinary and Plenipotentiary, Korea (1974–1978)
- *William Pennell Snow (1907–1986)
- Ambassador Extraordinary and Plenipotentiary, Burma (1959–1961)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (1961–1967)
- Archibald Loudon Snowden (1837–1912)
- Minister Resident/Consul General, Greece (1889–1891)
- Minister Resident/Consul General, Serbia (1889–1892)
- Minister Resident/Consul General, Romania (1889–1892)
- Envoy Extraordinary and Minister Plenipotentiary, Greece (1891–1892)
- Envoy Extraordinary and Minister Plenipotentiary, Serbia (1891)
- Envoy Extraordinary and Minister Plenipotentiary, Romania (1891–1892)
- Envoy Extraordinary and Minister Plenipotentiary, Spain (1892–1893)
- Clifford M. Sobel (1949–)
- Ambassador Extraordinary and Plenipotentiary, Netherlands (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Brazil (2006–2009)
- *Sidney Sober (1919–2014)
- Chargé d’Affaires ad interim, Pakistan (1973)
- Abraham D. Sofaer (1938–)
- Legal Adviser (1985–1990)
- *Earl David Sohm (1918–1995)
- Director of the Office of Management Policy (1975–1976)
- Mauricio Solaun (1935–)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (1977–1979)
- Howard E. Sollenberger (1917–1999)
- Director of the Foreign Service Institute (1971–1976)
- Anthony Morton Solomon (1919–2008)
- Assistant Secretary of State for Economic, Energy, and Business Affairs (1965–1969)
- Richard H. Solomon (1937–2017)
- Director of Policy Planning (1986–1989)
- Assistant Secretary of State for East Asian and Pacific Affairs (1989–1992)
- Ambassador Extraordinary and Plenipotentiary, Philippines (1992–1993)
- Alan D. Solomont (1949–)
- Ambassador Extraordinary and Plenipotentiary, Andorra (2009–2013)
- Ambassador Extraordinary and Plenipotentiary, Spain (2009–2013)
- William Clark Somerville (1790–1826)
- Chargé d’Affaires, Sweden (1825)
- Peter R. Sommer (1938–)
- Ambassador Extraordinary and Plenipotentiary, Malta (1987–1989)
- Gordon D. Sondland (?–)
- Representative of the U.S.A. to the European Union, with the rank and status of Ambassador Extraordinary and Plenipotentiary (2018)
- Tara D. Sonenshine (1959–)
- Under Secretary of State for Public Diplomacy and Public Affairs (2012–2013)
- *Helmut Sonnenfeldt (1926–2012)
- Counselor (1973–1977)
- William Brooks Sorsby (1858–1912)
- Envoy Extraordinary and Minister Plenipotentiary, Bolivia (1902–1908)
- Envoy Extraordinary and Minister Plenipotentiary, Honduras (1908)
- Michael Sotirhos (1928–2019)
- Ambassador Extraordinary and Plenipotentiary, Jamaica (1985–1989)
- Ambassador Extraordinary and Plenipotentiary, Greece (1989–1993)
- Pierre Soule (1801–1870)
- Envoy Extraordinary and Minister Plenipotentiary, Spain (1853–1855)
- John Glover South (1873–1940)
- Envoy Extraordinary and Minister Plenipotentiary, Panama (1921–1930)
- Envoy Extraordinary and Minister Plenipotentiary, Portugal (1929–1933)
- *Addison E. Southard (1884–1970)
- Minister Resident/Consul General, Ethiopia (1927–1934)
- *E. Michael Southwick (1945–)
- Ambassador Extraordinary and Plenipotentiary, Uganda (1994–1997)
- *James William Spain (1926–2008)
- Ambassador Extraordinary and Plenipotentiary, Tanzania (1975–1979)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1980–1981)
- Ambassador Extraordinary and Plenipotentiary, Maldives (1985–1989)
- Ambassador Extraordinary and Plenipotentiary, Sri Lanka (1985–1989)
- *Edward John Sparks (1897–1976)
- Ambassador Extraordinary and Plenipotentiary, Bolivia (1951–1954)
- Ambassador Extraordinary and Plenipotentiary, Guatemala (1955–1958)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (1958–1961)
- Ambassador Extraordinary and Plenipotentiary, Uruguay (1961–1962)
- *Moncrieff Johnston Spear (1921–)
- Chargé d’Affaires ad interim, The Bahamas (1973)
- Leonard H.O. Spearman (1929–2008)
- Ambassador Extraordinary and Plenipotentiary, Rwanda (1988–1990)
- Ambassador Extraordinary and Plenipotentiary, Lesotho (1990–1993)
- Daniel V. Speckhard (1959–)
- Ambassador Extraordinary and Plenipotentiary, Belarus (1997–2000)
- Ambassador Extraordinary and Plenipotentiary, Greece (2007–2010)
- Carroll Spence (1818–1896)
- Minister Resident, Turkey (1853–1857)
- Envoy Extraordinary and Minister Plenipotentiary, Turkey (Nomination of February 25, 1856, withdrawn before the Senate acted upon it.)
- Joan Edelman Spero (1944–)
- Under Secretary for Economic Growth, Energy, and the Environment (1993–1997)
- Watson Robertson Sperry (1842–1926)
- Minister Resident/Consul General, Iran (1892–1893)
- Daniel L. Spiegel (1945–)
- Representative of the U.S.A. to the European Office of the United Nations (Geneva) (1993–1995)
- Carl Spielvogel (1928–)
- Ambassador Extraordinary and Plenipotentiary, Slovakia (2000–2001)
- *Ronald Ian Spiers (1925–)
- Assistant Secretary of State for Politico-Military Affairs (1969–1973)
- Ambassador Extraordinary and Plenipotentiary, The Bahamas (1973–1974)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1977–1980)
- Assistant Secretary of State for Intelligence and Research (1980–1981)
- Ambassador Extraordinary and Plenipotentiary, Pakistan (1981–1983)
- Under Secretary of State for Management (1983–1989)
- Career Ambassador (1984)
- Herbert John Spiro (1924–2010)
- Ambassador Extraordinary and Plenipotentiary, Equatorial Guinea (1975–1976)
- Ambassador Extraordinary and Plenipotentiary, Cameroon (1975–1977)
- *Herbert Daniel Spivack (1917–2004)
- Chargé d’Affaires ad interim, Bangladesh (1972)
- Ronald Spogli (1948–)
- Ambassador Extraordinary and Plenipotentiary, Italy (2005–2009)
- Ambassador Extraordinary and Plenipotentiary, San Marino (2006–2009)
- *Pamela Leora Spratlen (1954–)
- Ambassador Extraordinary and Plenipotentiary, Kyrgyzstan (2011–2014)
- Ambassador Extraordinary and Plenipotentiary, Uzbekistan (2014–2018)
- Carroll Sprigg (1880–1944)
- Agent/Consul General, Egypt (1920–1921)
- George Stoney Springsteen Jr. (1923–1993)
- Executive Secretary (1974–1976)
- Director of the Foreign Service Institute (1976–1980)
- John T. Sprott (1933–)
- Ambassador Extraordinary and Plenipotentiary, Swaziland (1993–1996)
- *Philip Dodson Sprouse (1906–1977)
- Ambassador Extraordinary and Plenipotentiary, Cambodia (1962–1964)
- Raymond Ames Spruance (1886–1969)
- Ambassador Extraordinary and Plenipotentiary, Philippines (1952–1955)
- Ephraim George Squier (1821–1888)
- Chargé d’Affaires, Guatemala (1849)
- Herbert Goldsmith Squiers (1859–1911)
- Envoy Extraordinary and Minister Plenipotentiary, Cuba (1902–1905)
- Envoy Extraordinary and Minister Plenipotentiary, Panama (1906–1909)
- *Wells Stabler (1919–2009)
- Chargé d’Affaires ad interim, Jordan (1950)
- Ambassador Extraordinary and Plenipotentiary, Spain (1975–1978)
- *Walter Edward Stadtler (1936–)
- Ambassador Extraordinary and Plenipotentiary, Benin (1986–1989)
- *Joseph D. Stafford (1950–)
- Ambassador Extraordinary and Plenipotentiary, The Gambia (2004–2007)
- Chargé d’Affaires, Sudan (2014)
- John Bernhard Stallo (1823–1900)
- Envoy Extraordinary and Minister Plenipotentiary, Italy (1885–1889)
- William Harrison Standley (1872–1963)
- Ambassador Extraordinary and Plenipotentiary, Russia (1942–1943)
- *Sylvia Gaye Stanfield (1943–)
- Ambassador Extraordinary and Plenipotentiary, Brunei (1999–2002)
- *Edwin Forward Stanton (1901–1968)
- Envoy Extraordinary and Minister Plenipotentiary, Thailand (1946–1947)
- Ambassador Extraordinary and Plenipotentiary, Thailand (1947–1953)
- *Karen Clark Stanton (1955–)
- Ambassador Extraordinary and Plenipotentiary, Timor-Leste (2014–2017)
- *William A. Stanton (1947–)
- Chargé d’Affaires ad interim, Australia (2006)
- *George McDade Staples (1947–)
- Ambassador Extraordinary and Plenipotentiary, Rwanda (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Equatorial Guinea (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Cameroon (2001–2004)
- Director General of the Foreign Service (2006–2007)
- Craig Roberts Stapleton (1945–)
- Ambassador Extraordinary and Plenipotentiary, Czech Republic (2001–2003)
- Ambassador Extraordinary and Plenipotentiary, France (2005–2009)
- Envoy Extraordinary and Minister Plenipotentiary, Monaco (2006–2009)
- David Austin Starkweather (1802–1876)
- Envoy Extraordinary and Minister Plenipotentiary, Chile (1854–1857)
- *Gregory B. Starr (1953–)
- Assistant Secretary of State for Diplomatic Security (2013–2017)
- Harold E. Stassen (1907–2001)
- Director of the Foreign Operations Administration (1953–1955)
- Director of the Mutual Security Agency (1953)
- *Monteagle Stearns (1924–2016)
- Ambassador Extraordinary and Plenipotentiary, Côte d’Ivoire (1976–1979)
- Ambassador Extraordinary and Plenipotentiary, Greece (1981–1985)
- *Henry Endicott Stebbins (1905–1973)
- Ambassador Extraordinary and Plenipotentiary, Nepal (1959–1966)
- Ambassador Extraordinary and Plenipotentiary, Uganda (1966–1969)
- *William Perry Stedman Jr. (1923–2018)
- Ambassador Extraordinary and Plenipotentiary, Bolivia (1973–1977)
- Isaac Nevitt Steele (1809–1891)
- Chargé d’Affaires, Venezuela (1849–1853)
- *Howard Steers (?–)
- Chargé d’Affaires ad interim, Moldova ()
- *John Milton Steeves (1905–1998)
- Ambassador Extraordinary and Plenipotentiary, Afghanistan (1962–1966)
- Director General of the Foreign Service (1966–1969)
- William Raymond Steiger (1969–)
- Ambassador Extraordinary and Plenipotentiary, Mozambique (Nomination of January 10, 2007, not acted on by the Senate.)
- *Andrew Lee Steigman (1933–)
- Ambassador Extraordinary and Plenipotentiary, Gabon (1975–1977)
- Ambassador Extraordinary and Plenipotentiary, Sao Tome and Principe (1975–1977)
- *Robert Andrew Stein (1919–)
- Principal Officer, Yemen (1972)
- Chargé d’Affaires ad interim, Libya (1974)
- Chargé d’Affaires ad interim, Yemen ()
- Chargé d’Affaires ad interim, Mauritania ()
- *Donald K. Steinberg (1953–)
- Ambassador Extraordinary and Plenipotentiary, Angola (1995–1998)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (Nomination not acted upon by the Senate.)
- James Braidy Steinberg (1953–)
- Director of Policy Planning (1994–1996)
- Deputy Secretary of State (2009–2011)
- Laurence Adolph Steinhardt (1892–1950)
- Envoy Extraordinary and Minister Plenipotentiary, Sweden (1933–1937)
- Ambassador Extraordinary and Plenipotentiary, Peru (1937–1939)
- Ambassador Extraordinary and Plenipotentiary, Russia (1939–1941)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1942–1945)
- Ambassador Extraordinary and Plenipotentiary, Czechoslovakia (1944–1948)
- Ambassador Extraordinary and Plenipotentiary, Canada (1948–1950)
- Richard Allen Stengel (1955–)
- Under Secretary of State for Public Diplomacy and Public Affairs (2014–2016)
- *Ben Solomon Stephansky (1913–1999)
- Ambassador Extraordinary and Plenipotentiary, Bolivia (1961–1963)
- *Doris Kathleen Stephens (1953–)
- Ambassador Extraordinary and Plenipotentiary, Korea (2008–2011)
- *Barbara Jean Stephenson (1958–)
- Ambassador Extraordinary and Plenipotentiary, Panama (2008–2010)
- Thomas F. Stephenson (1942–)
- Ambassador Extraordinary and Plenipotentiary, Portugal (2007–2009)
- *Adam H. Sterling (1960–)
- Ambassador Extraordinary and Plenipotentiary, Slovakia (2016–2019)
- *Frederick Augustine Sterling (1876–1957)
- Envoy Extraordinary and Minister Plenipotentiary, Ireland (1927–1934)
- Envoy Extraordinary and Minister Plenipotentiary, Bulgaria (1933–1936)
- Envoy Extraordinary and Minister Plenipotentiary, Estonia (1937)
- Envoy Extraordinary and Minister Plenipotentiary, Latvia (1937)
- Envoy Extraordinary and Minister Plenipotentiary, Sweden (1938–1941)
- *Michael Edmund Sterner (1928–)
- Ambassador Extraordinary and Plenipotentiary, United Arab Emirates (1974–1976)
- John Batterson Stetson Jr. (1884–1952)
- Envoy Extraordinary and Minister Plenipotentiary, Finland (1925)
- Envoy Extraordinary and Minister Plenipotentiary, Poland (1925–1929)
- Edward Reilly Stettinius Jr. (1900–1949)
- Under Secretary of State (1943–1944)
- Secretary of State (1944–1945)
- Representative of the U.S.A. to the United Nations (1945–1946)
- *John Christopher Stevens (1960–2012)
- Ambassador Extraordinary and Plenipotentiary, Libya (2012)
- John Leavitt Stevens (1820–1895)
- Minister Resident, Paraguay (1870–1873)
- Minister Resident, Uruguay (1870–1873)
- Minister Resident, Sweden (1877–1883)
- Minister Resident, Hawaii (1889–1890)
- Envoy Extraordinary and Minister Plenipotentiary, Hawaii (1890–1893)
- Adlai Ewing Stevenson II (1900–1965)
- Representative of the U.S.A. to the United Nations (1961–1965)
- Andrew Stevenson (1784–1857)
- Envoy Extraordinary and Minister Plenipotentiary, United Kingdom (1836–1841)
- Envoy Extraordinary and Minister Plenipotentiary, United Kingdom (Nomination of May 20, 1834, rejected by the Senate.)
- John Reese Stevenson (1921–1997)
- Legal Adviser (1969–1973)
- *Robert Ayer Stevenson (1918–2000)
- Ambassador Extraordinary and Plenipotentiary, Malawi (1974–1978)
- *Susan N. Stevenson (?–)
- Ambassador Extraordinary and Plenipotentiary, Equatorial Guinea (2019)
- William Edwards Stevenson (1900–1985)
- Ambassador Extraordinary and Plenipotentiary, Philippines (1961–1964)
- *Charles Allen Stewart (1907–1973)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (1962–1964)
- *James Bolton Stewart (1882–1969)
- Envoy Extraordinary and Minister Plenipotentiary, Nicaragua (1942–1943)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (1943–1945)
- *John Todd Stewart (1940–)
- Ambassador Extraordinary and Plenipotentiary, Moldova (1995–1998)
- Joseph J. Stewart (?–)
- Minister Resident, Turkey (Not commissioned; nomination not confirmed by the Senate.)
- *Karen Brevard Stewart (1952–)
- Ambassador Extraordinary and Plenipotentiary, Belarus (2006–2008)
- Ambassador Extraordinary and Plenipotentiary, Laos (2010–2013)
- Ambassador Extraordinary and Plenipotentiary, Marshall Islands (2016–2020)
- Judith Ann Stewart-Stock (1946–)
- Assistant Secretary of State for Educational and Cultural Affairs (2010–2013)
- *William John Stibravy (1916–2013)
- Representative of the U.S.A. to the United Nations Industrial Development Organization (Vienna) (1968–1977)
- William Henry Stiles (1808–1865)
- Chargé d’Affaires, Austria (1845–1849)
- David Stilwell (?–)
- Assistant Secretary of State for East Asian and Pacific Affairs (2019)
- Thomas Neel Stilwell (1830–1874)
- Minister Resident, Venezuela (1867–1868)
- Edward W. Stimpson (1934–2009)
- Representative of the U.S.A. on the Council of the International Civil Aviation Organization (Montreal) (1999–2004)
- Harry Farnum Stimpson Jr. (1913–2005)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (1959–1961)
- Frederic Jesup Stimson (1855–1943)
- Ambassador Extraordinary and Plenipotentiary, Argentina (1914–1921)
- Henry Lewis Stimson (1867–1950)
- Secretary of State (1929–1933)
- Charles Richard Stith (1949–)
- Ambassador Extraordinary and Plenipotentiary, Tanzania (1998–2001)
- Francis Brown Stockbridge (1826–1894)
- Minister Resident, Netherlands (1875)
- Edward Grant Stockdale (1915–1963)
- Ambassador Extraordinary and Plenipotentiary, Ireland (1961–1962)
- Gilchrist Baker Stockton (1890–1972)
- Envoy Extraordinary and Minister Plenipotentiary, Austria (1930–1933)
- John Potter Stockton (1826–1900)
- Minister Resident, Holy See (1858–1861)
- Envoy Extraordinary and Minister Plenipotentiary, Austria (Not commissioned; nomination rejected by the Senate.)
- *Walter John Stoessel Jr. (1920–1986)
- Ambassador Extraordinary and Plenipotentiary, Poland (1968–1972)
- Assistant Secretary of State for European and Eurasian Affairs (1972–1974)
- Ambassador Extraordinary and Plenipotentiary, Russia (1973–1976)
- Ambassador Extraordinary and Plenipotentiary, Germany (1976–1981)
- Under Secretary of State for Political Affairs (1981–1982)
- Career Ambassador (1981)
- Deputy Secretary of State (1982)
- Secretary of State ad interim (1982)
- Edmund Stohr (1918–)
- Representative of the U.S.A. on the Council of the International Civil Aviation Organization (Montreal) (1982–1990)
- Carl Burton Stokes (1927–1996)
- Ambassador Extraordinary and Plenipotentiary, Seychelles (1994–1995)
- *William A. Stoltzfus Jr. (1924–)
- Ambassador Extraordinary and Plenipotentiary, Bahrain (1971–1974)
- Ambassador Extraordinary and Plenipotentiary, Kuwait (1971–1976)
- Ambassador Extraordinary and Plenipotentiary, Qatar (1971–1974)
- Ambassador Extraordinary and Plenipotentiary, Oman (1972–1974)
- Ambassador Extraordinary and Plenipotentiary, United Arab Emirates (1972–1974)
- *Galen Luther Stone (1921–)
- Ambassador Extraordinary and Plenipotentiary, Laos (1975)
- Ambassador Extraordinary and Plenipotentiary, Cyprus (1978–1981)
- Richard B. Stone (1928–)
- Ambassador at Large (1983–1984)
- Ambassador Extraordinary and Plenipotentiary, Denmark (1991–1993)
- *Robert Wilson Stookey (1917–1998)
- Chargé d’Affaires ad interim, Yemen (Was serving as Chargé d’Affaires ad interim when Legation Taiz was raised to Embassy status, Jan 28, 1963 (Embassy transferred to San’a in 1966).)
- *Mark C. Storella (1959–)
- Ambassador Extraordinary and Plenipotentiary, Zambia (2010–2013)
- Bellamy Storer (1847–1922)
- Envoy Extraordinary and Minister Plenipotentiary, Belgium (1897–1899)
- Envoy Extraordinary and Minister Plenipotentiary, Spain (1899–1902)
- Ambassador Extraordinary and Plenipotentiary, Austria (1902–1906)
- *James Story (?–)
- Chargé d’Affaires, Venezuela (2018)
- Edwin Wallace Stoughton (1818–1882)
- Envoy Extraordinary and Minister Plenipotentiary, Russia (1877–1879)
- Pleasant Alexander Stovall (1857–1935)
- Envoy Extraordinary and Minister Plenipotentiary, Switzerland (1913–1919)
- Jesse Isidor Straus (1872–1936)
- Ambassador Extraordinary and Plenipotentiary, France (1933–1936)
- Oscar Solomon Straus (1850–1926)
- Envoy Extraordinary and Minister Plenipotentiary, Turkey (1887–1889)
- Envoy Extraordinary and Minister Plenipotentiary, Turkey (1898–1899)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1909–1910)
- Robert Schwarz Strauss (1918–2014)
- U.S. Trade Representative (1977–1979)
- Ambassador Extraordinary and Plenipotentiary, Russia (1991–1992)
- Robert Strausz-Hupé (1903–2002)
- Ambassador Extraordinary and Plenipotentiary, Maldives (1970–1971)
- Ambassador Extraordinary and Plenipotentiary, Sri Lanka (1970–1971)
- Ambassador Extraordinary and Plenipotentiary, Belgium (1972–1974)
- Ambassador Extraordinary and Plenipotentiary, Sweden (1974–1976)
- U.S. Permanent Representative on the Council of the North Atlantic Treaty Organization (1976–1977)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1981–1989)
- Ambassador Extraordinary and Plenipotentiary, Morocco (Not commissioned; nomination withdrawn before the Senate acted upon it.)
- *Edward J. Streator (1930–)
- Representative of the U.S.A. to the Organization for Economic Cooperation and Development (Paris) (1984–1987)
- Gordon L. Streeb (1935–)
- Ambassador Extraordinary and Plenipotentiary, Zambia (1990–1993)
- Theodore Cuyler Streibert (1899–1987)
- Director of the U.S. Information Agency (1953–1956)
- Edward Henry Strobel (1855–1908)
- Third Assistant Secretary of State (1893–1894)
- Envoy Extraordinary and Minister Plenipotentiary, Ecuador (1894)
- Envoy Extraordinary and Minister Plenipotentiary, Chile (1894–1897)
- *Carl Walther Strom (1899–1969)
- Ambassador Extraordinary and Plenipotentiary, Cambodia (1956–1959)
- Ambassador Extraordinary and Plenipotentiary, Bolivia (1959–1961)
- Director of the Foreign Service Institute (1961–1962)
- *Eric Stromayer (1960–)
- Chargé d’Affaires ad interim, Comoros (2011)
- Chargé d’Affaires ad interim, Madagascar (2011)
- Ambassador Extraordinary and Plenipotentiary, Togo (2019)
- Lester Corrin Strong (1892–1966)
- Ambassador Extraordinary and Plenipotentiary, Norway (1953–1957)
- *Robert Campbell Strong (1915–1999)
- Ambassador Extraordinary and Plenipotentiary, Iraq (1963–1967)
- Thomas F. Stroock (1925–2009)
- Ambassador Extraordinary and Plenipotentiary, Guatemala (1989–1992)
- Cynthia Stroum (1950–)
- Ambassador Extraordinary and Plenipotentiary, Luxembourg (2009–2011)
- *James Curtis Struble (1953–)
- Ambassador Extraordinary and Plenipotentiary, Peru (2003–2007)
- Granville Stuart (1834–1918)
- Envoy Extraordinary and Minister Plenipotentiary, Paraguay (1894–1898)
- Envoy Extraordinary and Minister Plenipotentiary, Uruguay (1894–1898)
- John Leighton Stuart (1876–1962)
- Ambassador Extraordinary and Plenipotentiary, China (1946–1949)
- Robert D. Stuart (1916–2014)
- Ambassador Extraordinary and Plenipotentiary, Norway (1984–1989)
- R. Douglas Stuart (1886–1975)
- Ambassador Extraordinary and Plenipotentiary, Canada (1953–1956)
- *Wallace Wyman Stuart (1912–)
- Chargé d’Affaires ad interim, Panama (1964)
- James Flynn Stutesman (1860–1917)
- Envoy Extraordinary and Minister Plenipotentiary, Bolivia (1908–1910)
- *Roscoe Seldon Suddarth (1935–2013)
- Ambassador Extraordinary and Plenipotentiary, Jordan (1987–1990)
- Daniel S. Sullivan (1964–)
- Assistant Secretary of State for Economic, Energy, and Business Affairs (2006–2009)
- Jacob J. Sullivan (1976–)
- Director of Policy Planning (2011–2013)
- James Mark Sullivan (1873–1935)
- Envoy Extraordinary and Minister Plenipotentiary, Dominican Republic (1913–1915)
- John J. Sullivan (1959–)
- Deputy Secretary of State (2017)
- Ambassador Extraordinary and Plenipotentiary, Russia (2019)
- *Joseph Gerard Sullivan (1944–)
- Principal Officer, Cuba (1996)
- Ambassador Extraordinary and Plenipotentiary, Angola (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Zimbabwe (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (Nomination not acted upon by the Senate.)
- *Kevin K. Sullivan (1964–)
- Chargé d’Affaires ad interim, Argentina (2015)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (2018)
- Michael Sullivan (1939–)
- Ambassador Extraordinary and Plenipotentiary, Ireland (1998–2001)
- Peter John Sullivan (1821–1883)
- Minister Resident, Colombia (1867–1869)
- *Stephanie Sanders Sullivan (1958–)
- Ambassador Extraordinary and Plenipotentiary, Congo (Brazzaville) (2013–2017)
- Ambassador Extraordinary and Plenipotentiary, Ghana (2018)
- *William Healy Sullivan (1922–2013)
- Ambassador Extraordinary and Plenipotentiary, Laos (1964–1969)
- Ambassador Extraordinary and Plenipotentiary, Philippines (1973–1977)
- Ambassador Extraordinary and Plenipotentiary, Iran (1977–1979)
- *George Thomas Summerlin (1872–1947)
- Chargé d’Affaires ad interim, Mexico (1924)
- Envoy Extraordinary and Minister Plenipotentiary, Honduras (1925–1929)
- Envoy Extraordinary and Minister Plenipotentiary, Venezuela (1929–1935)
- Envoy Extraordinary and Minister Plenipotentiary, Panama (1934)
- Envoy Extraordinary and Minister Plenipotentiary, Panama (1935–1937)
- Chief of Protocol (1937)
- Allingham Burks Summers (1898–1977)
- Ambassador Extraordinary and Plenipotentiary, Luxembourg (1960–1961)
- Thomas Sumter Jr. (1768–1840)
- Minister Plenipotentiary, Portugal (1809–1819)
- Louis B. Susman (1937–)
- Ambassador Extraordinary and Plenipotentiary, United Kingdom (2009–2013)
- *Peter Adams Sutherland (1933–1994)
- Ambassador Extraordinary and Plenipotentiary, Bahrain (1980–1983)
- *James S. Sutterlin (1922–)
- Inspector General of the Department of State and the Foreign Service (1973–1974)
- Director of Policy Planning (1973)
- Geoffrey Swaebe (1911–1997)
- Representative of the U.S.A. to the European Office of the United Nations (Geneva) (1981–1983)
- Ambassador Extraordinary and Plenipotentiary, Belgium (1983–1988)
- *James Christopher Swan (1963–)
- Ambassador Extraordinary and Plenipotentiary, Djibouti (2008–2011)
- Ambassador Extraordinary and Plenipotentiary, Congo (Kinshasa) (2013–2016)
- *Emory Coblentz Swank (1922–2010)
- Ambassador Extraordinary and Plenipotentiary, Cambodia (1970–1973)
- *David Haywood Swartz (1942–)
- Ambassador Extraordinary and Plenipotentiary, Belarus (1992–1994)
- Alexander Sweek (1861–1950)
- Envoy Extraordinary and Minister Plenipotentiary, Thailand (Not commissioned; nomination not confirmed by the Senate.)
- Laurits Selmer Swenson (1865–1947)
- Envoy Extraordinary and Minister Plenipotentiary, Denmark (1897–1905)
- Envoy Extraordinary and Minister Plenipotentiary, Switzerland (1909–1911)
- Envoy Extraordinary and Minister Plenipotentiary, Norway (1911–1913)
- Envoy Extraordinary and Minister Plenipotentiary, Norway (1921–1930)
- Envoy Extraordinary and Minister Plenipotentiary, Netherlands (1931–1934)
- Richard Nelson Swett (1957–)
- Ambassador Extraordinary and Plenipotentiary, Denmark (1998–2001)
- John Franklin Swift (1829–1891)
- Envoy Extraordinary and Minister Plenipotentiary, Japan (1889–1891)
- *James W. Swihart Jr. (1946–)
- Ambassador Extraordinary and Plenipotentiary, Lithuania (1994–1997)
- Charles J. Swindells (1942–)
- Ambassador Extraordinary and Plenipotentiary, Samoa (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, New Zealand (2001–2005)
- *William Lacy Swing (1934–)
- Ambassador Extraordinary and Plenipotentiary, Congo (Brazzaville) (1979–1981)
- Ambassador Extraordinary and Plenipotentiary, Liberia (1981–1985)
- Ambassador Extraordinary and Plenipotentiary, South Africa (1989–1992)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (1992–1993)
- Ambassador Extraordinary and Plenipotentiary, Haiti (1993–1998)
- Ambassador Extraordinary and Plenipotentiary, Congo (Kinshasa) (1998–2001)
- James Wadsworth Symington (1927–)
- Chief of Protocol (1966–1968)
- John Fife Symington Jr. (1910–2007)
- Ambassador Extraordinary and Plenipotentiary, Trinidad and Tobago (1969–1971)
- *W. Stuart Symington IV (1952–)
- Ambassador Extraordinary and Plenipotentiary, Djibouti (2006–2008)
- Ambassador Extraordinary and Plenipotentiary, Rwanda (2008–2011)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (2016–2019)
- *Harrison Matthews Symmes (1921–2010)
- Ambassador Extraordinary and Plenipotentiary, Jordan (1967–1970)
- *Stephanie Syptak-Ramnath (?–)
- Chargé d’Affaires ad interim, Singapore (2019)